Intermolecular photoaddition involving 1,4-transfer of cyano group. 3 photoaddition of 2-cyanopyridine to olefins

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Abstract Photoreaction of 2-cyanopyridine with 2-methyl-2-butene and cyclopentene provided the corresponding annelated ketones 2 and 3, respectively, whereas photoreaction with 1-trimethylsilyloxycyclopentene afforded the “ene” product 8.

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