Blue spectral shift of P3HT organic film by KrF excimer laser ablation

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A technique for morphology control of self-assembled organic films based on laser ablation is presented. The regioregular poly 3-hexylthiophene (RR-P3HT) films prepared by using drop casting method and spin coating method are irradiated and ablated by the ultraviolet KrF excimer laser. Absorption spectra and XRD profiles of the films are investigated. For spin coated films, Blue absorption spectral shift is observed; For drop cast films, Blue shift in the absorption spectra, accompanied with the disappearance of the peak intensity of XRD profiles, are observed. The results indicate that molecular structure has been changed due to photo-thermal effect and molecule cutting effect of laser ablation.

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