Localized two liquids phase and non-metal-metal transition in the liquid STe system

書誌事項

公開日
1990-02-01
DOI
  • 10.1016/0022-3093(90)90596-e
公開者
Elsevier BV

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説明

Abstract Molar volume has been determined on the liquid STe system using a high energy gamma ray attenuation method. Overall dependence on temperature and concentration of the volume is quite similar to that reported for the liquid SeTe system. However anomalous behaviour was observed for S40Te60. The volume irregularly decreases around 680° C and recovers again around 740° C to the value extrapolated from the low temperatures, where a meniscus appears in the alloy. It has been found that the two liquids phase boundary is closed. The appearance of the lower and upper critical solution temperatures is discussed in relation to the structural change and the non-metal-metal transition in the liquid S, SeTe mixtures.

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