A Novel Titanium-Catalyzed Cyclization of Olefinic Iodoethers to Tetrahydrofurans

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A catalytic reductive cyclization of olefinic iodoethers was achieved by use of cat. Cp(2)TiCl(2) in the presence of Mn and Me(3)SiCl. This protocol provides a versatile method for the selective formation of multisubstituted tetrahydrofurans.

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