Assembly of a mixed-valence Cu(I/II) system coupled by multiple hydrogen bonding through tetrahydroxybenzoquinone
書誌事項
- 公開日
- 1998-02-01
- DOI
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- 10.1016/s0020-1693(97)05750-2
- 公開者
- Elsevier BV
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説明
Abstract The synthesis and characterization of a mixed-valence copper complex [CuII(bpy)2Cl]2[CuICl2]2(C6O6H4), where bpy = 2,2′-bipyridine, is described. The structure contains discrete copper(II) cation and copper(I) anion groups. In the cation each divalent copper is linked to two bpy molecules and one chloride ion in a trigonal bipyramidal fashion, whereas in the anion each monovalent copper is linearly bound to two chlorine atoms. The mixed-valence Cu(I/II) system is associated by multiple hydrogen bonding through tetrahydroxybenzoquinone, leading to an infinite chain structure of the complex. The complex was also characterized by spectroscopic studies.
収録刊行物
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- Inorganica Chimica Acta
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Inorganica Chimica Acta 268 317-321, 1998-02-01
Elsevier BV