A new stereoselective synthesis of 2-subsdtituted 1,3-bis(trimethylsilyl)propene derivatives and their conversion to cyclopentane and cyclohexane derivatives
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説明
Abstract Ester 2 on treatment with sodium salt of sulfone or sulfoxide afforded 2-substituted 1,3-bis(trimethylsily)propene 3 in good yield, from which cyclopentane and cyclohexane derivatives bearing a trimethylsilyl group in the molecules were synthesized.
収録刊行物
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- Tetrahedron Letters
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Tetrahedron Letters 23 5419-5422, 1982-01-01
Elsevier BV