Unique formation of two different W/Ag/S clusters from the same components via a low heating temperature solid state reaction and a solution reaction and their third-order NLO properties in solutionElectronic supplementary information (ESI) available: experimental: general comments, synthesis of complexes, third-order NLO measurements, time response spectra. See http://www.rsc.org/suppdata/cc/b1/b107251j/

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説明

Reaction of (NH4)2[WS4], [Ag(MeCN)4](PF6) and dppm (molar ratio = 1∶2∶4) in the solid state at 110 °C followed by extraction with CH2Cl2 yielded a hexanuclear neutral cluster [(WS4)2Ag4(dppm)3] 1, while the same materials when mixed directly in CH2Cl2 produced a tetranuclear cluster salt [WS4Ag3(dppm)4](PF6) 2; both compounds showed modest third-order optical nonlinearities.

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詳細情報 詳細情報について

  • CRID
    1871709543027652096
  • DOI
    10.1039/b107251j
  • ISSN
    1364548X
    13597345
  • データソース種別
    • OpenAIRE

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