Dynamics of Photd-Induced Phase-Transition in Low Dimensional Organic Crystals and the Role of Phomcarriers

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We report the dynamics of a unique photo-induced phenomenon in quasi-one-dimensional organic crystals; i. e. phase transitions triggered by photo-excitation in conjugated polymers and charge-transfer crystals. Nano-second and pico-second time-resolved studies indicate that photo-generated charge-carriers (bi-polarons) play an important role in the driving process of the photo-induced phase transition (PIPT)

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