Reductions with the lithium aluminium hydride‐poly(<i>N</i>‐methylethyleneimine) complex suspended in hydrocarbon media

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<jats:title>Abstract</jats:title><jats:p>A variant of the reduction with lithium aluminium hydride (LAH), involving the complex of LAH with a high‐molecular‐weight, linear poly(<jats:italic>N</jats:italic>‐methylethyleneimine) (PMEI), is described. The reduction of simple aldehydes, ketones, or esters was found to proceed essentially within the solid LAH‐PMEI complex suspended in pentane and the resulting pure alcohols can be isolated by working up only the separated solid phase.</jats:p>

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