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説明
<jats:title>Abstract</jats:title><jats:p>The La–Li–(<jats:italic>R</jats:italic>)‐BINOL complex prepared from either lanthanum(III) chloride [LaCl<jats:sub>3</jats:sub> · 7H<jats:sub>2</jats:sub>O] or [La(O‐i‐Pr)<jats:sub>3</jats:sub>] has made possible effective catalytic asymmetric syntheses of therapeutically important ß‐blockers such as propranolol and metoprolol. The possible stereochemical course of asymmetric nitroaldol reactions has been also clarified.</jats:p>
収録刊行物
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- Applied Organometallic Chemistry
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Applied Organometallic Chemistry 9 421-426, 1995-08-01
Wiley