Activation and synthetic applications of thiostannanes

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<jats:title>Abstract</jats:title><jats:p>Acetals of various aldehydes and ketones, e.g. (I), are converted into the corresponding monothioacetals, e.g. (II), under mild conditions through activating of the Sn‐S bonds in the thiostannane (III) in the presence of BF<jats:sub>3</jats:sub>·Et<jats:sub>2</jats:sub>O. The reaction likewise proceeds quantitatively with cyclic ethers, e.g. (IV) (→ (V)).</jats:p>

収録刊行物

  • Tetrahedron

    Tetrahedron 45 1209-1218, 1989-01-01

    Elsevier BV

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