Synthesis of Thiophene-Fused Siloles through Rhodium-Catalyzed Trans-Bis-Silylation

Akinobu Naka, Maho Inoue, Haruna Kawabe, Hisayoshi Kobayashi

doi:10.3390/appliedchem4010003

説明

<jats:p>Rhodium-catalyzed reactions of 3-ethynyl-2-pentamethyldisilanylthiophene derivatives (1a–1c) have been reported. At 110 °C, compounds 1a–1c reacted in the presence of a rhodium complex catalyst, yielding thiophene-fused siloles (2a–2c) through intramolecular trans-bis-silylation. To understand the production of 2a from 1a, the mechanism was investigated using density functional theory (DFT) calculations.</jats:p>

収録刊行物

AppliedChem

AppliedChem 4 29-41, 2024-02-02

MDPI AG

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詳細情報詳細情報について

CRID: 1872273591444333312

DOI: 10.3390/appliedchem4010003

ISSN: 26739623

本文言語コード: en

データソース種別

OpenAIRE

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