RAMAN SPECTRA OF TITANIUM DI-, TRI-, AND TETRA-CHLORIDES

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<jats:p> We have obtained the Raman spectra of TiCl <jats:sub>n</jats:sub> (n= 2, 3, and 4). Assignments of the observed Raman bands were made by a normal mode analysis. The force constants were determined from the observed Raman band frequencies. We have found that the Ti-Cl stretching force constant increases as the oxidation number of the Ti species increases. </jats:p>

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