Effects of β-substituents on internal rotation of the anthryl group of 2-anthrylethylenes in the excited singlet state

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Abstract 2-Vinylanthracene and its β-alkyl derivatives undergo, in the excited singlet state, almost one-way rotational isomerization around the single bond connecting the anthracene nucleus and CC double bond, while no rotational isomerization takes place for 2-anthrylethylenes with a phenyl or 2-naphthyl group in the β-position.

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