Reaction of 2-t-butyl-1,3-butadiene with π-allylic palladium complexes. A novel cyclization of allylilc ligands
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説明
Abstract The reaction of 2-t-butyl-1,3-butadiene with π-allylic palladium chlorides is described. The 2-chloroallyl complex gives a π-allylic complex with an open chain structure, in which the butenyl group in is the anti-position. Allyl-1-carbomethoxyallyl-, methallyl-, and 1-carbomethoxymethallyl-palladium chlorides give six-membered cyclic complexes. The product of the former two are π-allyllic and those of the latter are σ-bonded complexes.
収録刊行物
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- Journal of Organometallic Chemistry
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Journal of Organometallic Chemistry 140 317-323, 1977-11-01
Elsevier BV