Development of a new sterically protecting auxiliary of the metacyclophane type and application to unsymmetrical diphosphene, 1,3-diphosphaallene, and 1,4-diphosphabutatrieneElectronic supplementary information (ESI) available: Physical data. See http://www.rsc.org/suppdata/cc/b2/b209666h/

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説明

A new bulky bromobenzene of the metacyclophane type was converted to an unsymmetrically substituted 1,4-diphos-phabutatriene whose spin-spin coupling constant (3Jpp) turned out to be larger, for the first time, than the 2Jpp value of the corresponding 1,3-diphosphaallene.

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詳細情報 詳細情報について

  • CRID
    1873116917302780288
  • DOI
    10.1039/b209666h
  • ISSN
    1364548X
    13597345
  • PubMed
    12536792
  • データソース種別
    • OpenAIRE

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