Photochemical oxidative CαCβ bond cleavage of tryptophan side-chain by pyrimido[5,4-]pteridine -oxide

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Abstract Tryptophan derivatives 1 undergo with ease the oxidative CαCβ bond cleavage by pyrimido[5,4- g ]pteridine N -oxide 2 under irradiation with UV-visible light in the presence of acid-catalyst to give 3-indolecarboxaldehydes 3 and the corresponding glycine derivatives 4 .

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