Stereoselective total synthesis of polyether ionophore antibiotics, isolasalocid A and lasalocid A. part 2. the total synthesis via stereoselective construction of the B rings by chelation-controlled cyclization under thermodynamic conditions.

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Abstract Stereoselective total synthesis of isolasalocid A ( 1 ) and lasalocid A ( 2 ) was achieved via construction of the tetrahydrofuran rings by chelation-controlled cyclization of the corresponding p -methoxyphenyl substituted allyl alcohols ( 6, 7 ) under thermodynamic conditions.

Journal

  • Tetrahedron

    Tetrahedron 49 5997-6018, 1993-07-01

    Elsevier BV

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