Ring-Expansion of Bridgehead Aldehydes with 1-Adamantanecarbonyl Cation or Benzoyl Trifluoromethanesulfonate: A New Route to Bicyclic and Tricyclic 1,2-Diols

Ken'ichi Takeuchi, Itsuko Kitagawa, Fumio Akiyama, Tadashi Shibata, Midori Kato, Kunio Okamoto

doi:10.1002/chin.198750141

【2025年5月12日更新】CiNii Dissertations及びCiNii BooksのCiNii Researchへの統合について
CiNii Researchナレッジグラフ検索機能（試行版）をCiNii Labsにて公開しました
【2025年6月30日更新】日経BP社提供データの更新停止及び削除について
「研究データ」「根拠データ」の収録について

Ring-Expansion of Bridgehead Aldehydes with 1-Adamantanecarbonyl Cation or Benzoyl Trifluoromethanesulfonate: A New Route to Bicyclic and Tricyclic 1,2-Diols

DOI DOI PDF 被引用文献1件

Ken'ichi Takeuchi
Itsuko Kitagawa
Fumio Akiyama
Tadashi Shibata
Midori Kato
Kunio Okamoto

この論文をさがす

CiNii Books

説明

<jats:title>Abstract</jats:title><jats:p>Ring‐expansion of the norbornene‐1‐aldehyde (I) is achieved by acylation with benzoyl or 1‐adamantylcarbonyl triflate and subsequent basic hydrolysis to produce bicyclo(2.2.2)octane‐1,2‐diol (III).</jats:p>