Two distinct conformational isomers of the 16-membered epoxyenone, the key synthetic intermediate of maridonolides. Conformational analysis and completely stereoselective reduction of the C9 carbonyl group1)
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説明
Abstract The key synthetic intermediate of maridonolides ( 2 ) has two easily detectable conformational isomers in solution. The conformational analysis of the 16-membered epoxyenone ring and the effect of conformation on reactivity in the reduction of the C9 carbony group are described.
収録刊行物
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- Tetrahedron Letters
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Tetrahedron Letters 32 5133-5136, 1991-09-01
Elsevier BV