Anomeric effect on kinetic acidity: Examples for the oxygen atom of ethers to accelerate abstraction of an α-hydrogen atom
説明
Abstract In contrast with general observation, two different types of experiments indicate that the abstraction of α-hydrogen atom of ether having proper conformation is slightly enhanced by the oxygen atom in line with our previous AM1 calculation.
収録刊行物
-
- Tetrahedron Letters
-
Tetrahedron Letters 34 3429-3432, 1993-05-01
Elsevier BV
