Study of the mechanism for the rearrangement of thiolsulfinate with acetic anhydride by 13C- and 18O-Tracer experiments
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説明
Abstract Recently, we found that benzyl phenylmethanethiolsulfinate (I) reacts with acetic anhydride at 60°C to afford the rearranged sulfoxide, i.e., an almost 1:1 mixture of both erythro and threo-1-(acetoxylthio)benzyl benzyl sulfoxides(II) in a substantial yield.
収録刊行物
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- Tetrahedron Letters
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Tetrahedron Letters 19 1567-1570, 1978-01-01
Elsevier BV