Use of aluminium as an electron pool. Reductive coupling of iodobenzenes promoted by electron transfer in an Ni/Pb/A1 multi redox system

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Abstract Reductive coupling of iodobenzenes was achieved successfully by use of a stoichiometric amount of aluminium metal as an electron source and catalytic amounts of NiCl2(bpy) (bpy=2,2 - bipyridyl) and lead(II) bromide as electron transfer catalysts in methanol containing potassium iodide.

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