Investigation of SO_3 absorption line for in situ gas detection inside combustion plants using a 4-μm-band laser source
説明
We have investigated 4-μm-band SO3 absorption lines for in situSO3 detection using a mid-infrared laser source based on difference frequency generation in a quasi-phase-matched LiNbO3 waveguide. In the wavelength range of 4.09400–4.10600 μm, there were strong SO3 absorption lines. The maximum absorption coefficient at a concentration of 170 ppmv was estimated to be about 3.2×10−5 cm−1 at a gas temperature of 190°C. In coexistence with H2O, the reduction of the SO3 absorption peak height was observed, which was caused by sulfuric acid formation. We discuss a method of using an SO3 equilibrium curve to derive the total SO3 molecule concentration.
収録刊行物
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- Applied Optics
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Applied Optics 55 6887-, 2016-08-24
Optica Publishing Group
