Synthesis and characterization of black phosphorus intercalation compounds

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Abstract Black Phosphorus-Iodine intercalation compounds have been synthesized for the first time. Favorable reaction conditions for the synthesis and intercalated structures have been revealed. Temperature dependence of electrical conductivities of black phosphorus single crystals significantly changes after intercalation and in some cases a metallic phase is realized down to 1.5 K. Moreover, it is noted that the conduction behavior is rather sensitive to the atmosphere in the reaction, namely a trace of moisture.

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