High-precision micro-combustion calorimetry of anthracene

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Abstract A high-precision micro-combustion calorimeter was developed. Details of the calorimeter are described. The energy equivalent of the calorimeter and the standard deviation of the mean were determined to be (67.8330  ±  0.0024)J · K − 1after calibration with thermochemical standard benzoic acid (five experiments). The standard enthalpy of combustion of anthracene was determined to be  − (7065.0  ±  1.1)kJmol − 1.

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