Structure determination and absolute configuration of pisiferdiol,a new phenolic diterpenoid with a rearranged abietane skeleton from End1

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Description

Abstract Pisiferdiol 1 , isolated from C. pisifera , was shown to be a new phenolic diterpenoid with a rearranged abietane skeleton. The structure was established by several degradation reactions and from spectral evidence including LSPD experiments and NOE difference spectra. The absolute configuration was determined by employing the dibenzoate exciton chirality method on the di-p-bromobenzoate 12 .

Journal

  • Tetrahedron

    Tetrahedron 42 529-535, 1986-01-01

    Elsevier BV

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