Claisen and Intermolecular Rearrangement of Cinnamyloxynaphthalenes
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説明
Rearrangements of the 1- and 2-cinnamyloxynaphthalenes undergo in diethylene glycol and decalin with solvent de-pendence. In 2-cinnamyloxynaphthalene, the Claisen rearrangement occurs regardless of the solvents. However, for the 1-analogue, the Claisen rearrangement occurs in decalin, while both the Claisen and intermolecular rearrangements occur at higher temperatures in diethylene glycol.
収録刊行物
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- International Journal of Organic Chemistry
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International Journal of Organic Chemistry 02 38-43, 2012-01-01
Scientific Research Publishing, Inc.
