An optically active allene macrodiolide: A versatile key intermediate leading to (−)-pyrenophorin and (+)-dibenzomacrodiolides

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<jats:title>Abstract</jats:title><jats:p>The key step in the synthesis of the allene macrodiolides (VII) is the dimerization of the ω‐chlorocarbonylphosphonium bromides (VI) via olefination of the intermediately formed ketones.</jats:p>

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