Shaping the Magnetic Properties of BaFeO<sub>3</sub> Perovskite-Type by Alkaline-Earth Doping
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- Nguyen Hoa Hong
- Nanomagnetism Laboratory, Department of Physics and Astronomy, Seoul National University, Gwanak-gu, Seoul 08826, South Korea
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- Mohammed Benali Kanoun
- College of Science, Department of Physics, Alfaisal University, P.O. Box 50927 Riyadh, Saudi Arabia
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- Jang-Gun Kim
- Nanomagnetism Laboratory, Department of Physics and Astronomy, Seoul National University, Gwanak-gu, Seoul 08826, South Korea
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- Timur Sh. Atabaev
- Nanomagnetism Laboratory, Department of Physics and Astronomy, Seoul National University, Gwanak-gu, Seoul 08826, South Korea
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- Kensuke Konishi
- Department of Physics, Graduate School of Science and Engineering, Ehime University, 2-5 Bunkyo-cho, Matsuyama 790-8577, Japan
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- Satoshi Noguchi
- Department of Physics, Graduate School of Science and Engineering, Ehime University, 2-5 Bunkyo-cho, Matsuyama 790-8577, Japan
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- Makio Kurisu
- Department of Physics, Graduate School of Science and Engineering, Ehime University, 2-5 Bunkyo-cho, Matsuyama 790-8577, Japan
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- Souraya Goumri-Said
- College of Science, Department of Physics, Alfaisal University, P.O. Box 50927 Riyadh, Saudi Arabia
書誌事項
- 公開日
- 2018-01-25
- DOI
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- 10.1021/acs.jpcc.7b10127
- 公開者
- American Chemical Society (ACS)
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説明
The alkaline-earth iron perovskites AFeO3 are interesting materials since their ferromagnetic domains could be controlled by an applied magnetic field. However, to be exploited for applications, there are still some flaws related to their antiferromagnetic or ferromagnetic behavior at low temperatures. In our work, we have attempted to synthesize pristine BaFeO3 with Ba to partially or fully substitute Sr or Ca in order to tailor the magnetic properties of the host compound as expected for applications. We found that powders of (Ca/Sr/Ba) FeO3 showed an increased enhancement of magnetic properties in comparison to BaFeO3 films. In particular, the (Ca/Sr)0.5Ba0.5FeO3 nanopowders have demonstrated a Curie temperature well above room temperature along with an increased magnetic moment. A considerable coercivity is also surprisingly obtained as a typical signature for a hard magnetic material. First-principles calculations were performed to get an insight into the Ca/Sr influence on the lattice structure, and...
収録刊行物
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- The Journal of Physical Chemistry C
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The Journal of Physical Chemistry C 122 (5), 2983-2989, 2018-01-25
American Chemical Society (ACS)
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詳細情報 詳細情報について
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- CRID
- 1360588387116356224
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- ISSN
- 19327455
- 19327447
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- データソース種別
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- Crossref
- OpenAIRE