Regioselective olefin arylation catalyzed by [Ir(acac)2Cl]2 with base

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Abstract By addition of bases to remove Cl in situ, [Ir(acac) 2 Cl] 2 was found to work as a catalyst for anti-Markovnikov arylation of olefin with benzene to produce straight-chain alkylbenzene in higher selectivity than the branched alkylbenzene the same as [Ir(acac) 3 ] 2 .

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