書誌事項
- タイトル別名
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- Evaluation of interfacial adhesion energy between polystyrene and silica gel-filler immobilizing hydroxybenzophenone by use of surface tension analysis by wicking method
- モウカン シントウホウ ニ ヨル ヒョウメン チョウリョク ソクテイ オ リヨウ シタ ポリスチレン ト ヒドロキシベンゾフェノン コテイカ シリカゲル フィラー カン ノ カイメン エネルギー ノ ミツモリ
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説明
Hydroxybenzophenone group (Hbp)-immobilized silica gel-fillers (1) acting as UV-absorber were prepared. Surface tensions (γ) of 1 were measured by the wicking method. The interfacial adhesion energy (W) of the composites (l/PS) between 1 and the polystyrene (PS) was calculated using the dispersive component (γ^D) and the polar component (γ^P) of γ according to the equation described below where subscripts m and f mean matrix and filler, respectively. The W values of the l/PS composites were considerably smaller than those of the parent SiO_2/PS composite. A good correlation between W and glass transition temperature (T_g) showed that an introduction of Hbp groups on SiO_2 was effective for enhancement of adhesion between the 1 and matrix polymer. W=2√<γ^D_f・γ^D_m>+2√<γ^P_f・γ^P_m>
収録刊行物
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- 宮崎大学工学部紀要
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宮崎大学工学部紀要 40 23-28, 2011-07-30
宮崎大学工学部
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詳細情報 詳細情報について
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- CRID
- 1050007314763135744
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- NII論文ID
- 110008667581
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- NII書誌ID
- AA00732558
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- ISSN
- 05404924
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- HANDLE
- 10458/3586
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- NDL書誌ID
- 11203397
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- 本文言語コード
- ja
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- 資料種別
- departmental bulletin paper
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- データソース種別
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- IRDB
- NDL
- CiNii Articles