4-Amino-TEMPO-Immobilized Polymer Monolith: Preparations, and Recycling Performance of Catalyst for Alcohol Oxidation

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  • Imoto, Tomoki
    Department of Chemical Engineering, Graduate School of Engineering, Kyushu University
  • Matsumoto, Hikaru
    Department of Chemical Engineering, Graduate School of Engineering, Kyushu University
  • Nonaka, Seiya
    Department of Chemical Engineering, Graduate School of Engineering, Kyushu University
  • Shichijo, Keita
    Department of Applied Chemistry, Graduate School of Engineering, Kyushu University
  • Nagao, Masanori
    Department of Chemical Engineering, Graduate School of Engineering, Kyushu University
  • Shimakoshi, Hisashi
    Department of Applied Chemistry, Graduate School of Engineering, Kyushu University
  • Hoshino, Yu
    Department of Chemical Engineering, Graduate School of Engineering, Kyushu University Department of Applied Chemistry, Graduate School of Engineering, Kyushu University
  • Miura, Yoshiko
    Department of Chemical Engineering, Graduate School of Engineering, Kyushu University

Description

Continuous flow reactors with immobilized catalysts are in great demand in various industries, to achieve easy separation, regeneration, and recycling of catalysts from products. Oxidation of alcohols with 4-amino-TEMPO-immobilized monolith catalyst was investigated in batch and continuous flow systems. The polymer monoliths were prepared by polymerization-induced phase separation using styrene derivatives, and 4-amino-TEMPO was immobilized on the polymer monolith with a flow reaction. The prepared 4-amino-TEMPO-immobilized monoliths showed high permeability, due to their high porosity. In batch oxidation, the reaction rate of 4-amino-TEMPO-immobilized monolith varied with stirring. In flow oxidation, the eluent permeated without clogging, and efficient flow oxidation was possible with residence times of 2–8 min. In the recycling test of the flow oxidation reaction, the catalyst could be used at least six times without catalyst deactivation.

Journal

  • Polymers

    Polymers 14 (23), 5123-, 2022-11-24

    MDPI

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