4-Amino-TEMPO-Immobilized Polymer Monolith: Preparations, and Recycling Performance of Catalyst for Alcohol Oxidation
書誌事項
- 公開日
- 2022-11-24
- 資源種別
- journal article
- 権利情報
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- Creative Commons Attribution 4.0 International
- © 2022 by the authors.
- DOI
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- 10.3390/polym14235123
- 公開者
- MDPI
説明
Continuous flow reactors with immobilized catalysts are in great demand in various industries, to achieve easy separation, regeneration, and recycling of catalysts from products. Oxidation of alcohols with 4-amino-TEMPO-immobilized monolith catalyst was investigated in batch and continuous flow systems. The polymer monoliths were prepared by polymerization-induced phase separation using styrene derivatives, and 4-amino-TEMPO was immobilized on the polymer monolith with a flow reaction. The prepared 4-amino-TEMPO-immobilized monoliths showed high permeability, due to their high porosity. In batch oxidation, the reaction rate of 4-amino-TEMPO-immobilized monolith varied with stirring. In flow oxidation, the eluent permeated without clogging, and efficient flow oxidation was possible with residence times of 2–8 min. In the recycling test of the flow oxidation reaction, the catalyst could be used at least six times without catalyst deactivation.
収録刊行物
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- Polymers
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Polymers 14 (23), 5123-, 2022-11-24
MDPI
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詳細情報 詳細情報について
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- CRID
- 1050018816303646336
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- ISSN
- 20734360
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- HANDLE
- 2324/7161838
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- PubMed
- 36501517
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- 本文言語コード
- en
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- 資料種別
- journal article
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- データソース種別
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- IRDB
- Crossref
- KAKEN
- OpenAIRE
