Enantioselective C-H amidation of sulfondiimines for the synthesis of 1,2,4-benzothiadiazine-1-imines under cobalt catalysis
書誌事項
- 公開日
- 2025-08-07
- 資源種別
- journal article
- 権利情報
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- © the Partner Organisations 2025
- This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
- DOI
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- 10.1039/d5qo00355e
- 公開者
- Royal Society of Chemistry (RSC)
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説明
In comparison to the notable recent progress in the derivatization of sulfoximines via directed C–H activation, the C–H activation/functionalization of sulfondiimines is underdeveloped. Here, we report C–H amidation/cyclization reactions of sulfondiimines with dioxazolones catalyzed by the combination of a cobalt(III) catalyst and a pseudo C₂-symmetric chiral carboxylic acid, leading to the formation of unprecedented 1,2,4-benzothiadiazine-1-imine structures in high enantioselectivity.
収録刊行物
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- Organic Chemistry Frontiers
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Organic Chemistry Frontiers 12 (15), 4236-4241, 2025-08-07
Royal Society of Chemistry (RSC)
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詳細情報 詳細情報について
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- CRID
- 1050586499778570496
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- ISSN
- 20524129
- 20524110
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- HANDLE
- 2433/295322
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- 本文言語コード
- en
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- 資料種別
- journal article
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- データソース種別
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