Photoliquefaction and phase transition of m-bisazobenzenes give molecular solar thermal fuels with a high energy density

DOI IR (HANDLE) Web Site Research Data 36 References Open Access
  • Morikawa, Masa-aki
    Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University Center for Molecular Systems (CMS), Kyushu University
  • Yamanaka, Yuta
    Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University
  • Joseph Ka Ho Hui
    Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University
  • Kimizuka, Nobuo
    Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University Center for Molecular Systems (CMS), Kyushu University Research Center for Negative Emissions Technologies, Kyushu University (K-NETs)

Bibliographic Information

Other Title
  • Photoliquefaction and phase transition of <i>m</i>-bisazobenzenes give molecular solar thermal fuels with a high energy density

Description

<jats:p>(<jats:italic>E</jats:italic>,<jats:italic>E</jats:italic>)-<jats:italic>m</jats:italic>-bisazobenzenes show photoliquefaction to liquid <jats:italic>Z</jats:italic>-bisazobenzenes, which reveal exothermicity due to <jats:italic>Z</jats:italic>-to-<jats:italic>E</jats:italic> isomerization and liquid-to-solid phase changes, with a high gravimetric heat storage capacity of up to 392 J g<jats:sup>−1</jats:sup>.</jats:p>

Journal

  • RSC Advances

    RSC Advances 13 (34), 24031-24037, 2023

    Royal Society of Chemistry (RSC)

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