Perfluoroalkylation of Unactivated Alkenes with Acid Anhydrides as the Perfluoroalkyl Source

DOI Web Site Web Site 被引用文献11件 参考文献61件
  • Shintaro Kawamura
    Synthetic Organic Chemistry Laboratory RIKEN 2-1 Hirosawa, Wako Saitama 351-0198 Japan
  • Mikiko Sodeoka
    Synthetic Organic Chemistry Laboratory RIKEN 2-1 Hirosawa, Wako Saitama 351-0198 Japan

書誌事項

公開日
2016-06-02
資源種別
journal article
権利情報
  • http://onlinelibrary.wiley.com/termsAndConditions#vor
DOI
  • 10.1002/anie.201604127
公開者
Wiley

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説明

<jats:title>Abstract</jats:title><jats:p>An efficient perfluoroalkylation of unactivated alkenes with perfluoro acid anhydrides was developed. Copper salts play a crucial role as a catalyst to achieve allylic perfluoroalkylation with the in situ generated bis(perfluoroacyl) peroxides. Furthermore, carboperfluoroalkylation of alkene bearing an aromatic ring at an appropriate position on the carbon side chain was found to proceed under metal‐free conditions to afford carbocycles or heterocycles bearing a perfluoroalkyl group. This method, which makes use of readily available perfluoroalkyl sources, offers a convenient and powerful tool for introducing a perfluoroalkyl group onto an sp<jats:sup>3</jats:sup> carbon to construct synthetically useful skeletons.</jats:p>

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