Reversible Emergence of a Self-Assembled Layered Structure From Three-Dimensional Isotropic Ionic Crystal of a Cluster Compound (4-HNC<sub>5</sub>H<sub>4</sub>OH)<sub>2</sub>Mo<sub>6</sub>Cl<sub>14</sub> Driven By Absorption of Water and Alcohols
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- Kei Inumaru
- Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, 1-4-1, Kagamiyama, Higashi-Hiroshima 739-8527, Japan
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- Takashi Kikudome
- Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, 1-4-1, Kagamiyama, Higashi-Hiroshima 739-8527, Japan
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- Hiroshi Fukuoka
- Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, 1-4-1, Kagamiyama, Higashi-Hiroshima 739-8527, Japan
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- Shoji Yamanaka
- Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, 1-4-1, Kagamiyama, Higashi-Hiroshima 739-8527, Japan
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説明
The compound comprising nanometer scale cluster molecules showed unusual reversible structural transformation between an isotropic ionic crystal and a layered structure of which the interlayer spaces are filled with the absorbed molecules.
収録刊行物
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- Journal of the American Chemical Society
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Journal of the American Chemical Society 130 (31), 10038-10039, 2008-07-10
American Chemical Society (ACS)
