Synthesis, Structure, and Catalysis of Palladium Complexes Bearing a Group 13 Metalloligand: Remarkable Effect of an Aluminum-Metalloligand in Hydrosilylation of CO<sub>2</sub>

DOI Web Site 研究データあり 被引用文献34件 参考文献44件
  • Jun Takaya
    Department of Chemistry, School of Science, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8551, Japan
  • Nobuharu Iwasawa
    Department of Chemistry, School of Science, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8551, Japan

書誌事項

公開日
2017-04-25
資源種別
journal article
DOI
  • 10.1021/jacs.7b02553
公開者
American Chemical Society (ACS)

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説明

Efficient synthesis and catalysis of a series of palladium complexes having a group 13 metalloligand (Al, Ga, In) are reported utilizing 6,6″-bis(phosphino)terpyridine as a new scaffold for Pd–E bonds (E = Al, Ga, In). Systematic investigation revealed unique characteristics of the Al-metalloligand in both structure and reactivity, which exhibited the highest catalytic activity for hydrosilylation of CO2 ever reported (TOF = 19 300 h–1). This study demonstrated fine-tuning of catalyst activity by the precisely designed metalloligand is a promising approach for new catalyst development in synthetic organometallic chemistry.

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