Excess Thermodynamic Properties of Ternary Mixtures of <i>N</i>-Methylcyclohexylamine and Toluene with 1-Alcohols
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- Losetty Venkatramana
- Department of Chemistry, P.V.K.N. Govt. Degree & P.G. College
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- C Narasimha Rao
- Department of Chemistry, Sri Venkateswara University
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- Kasibhatta Siva Kumar
- Department of Chemistry, S.V. Arts UG & PG College
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- Ramesh L Gardas
- Department of Chemistry, Indian Institute of Technology Madras
書誌事項
- 公開日
- 2014-08-26
- 権利情報
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- https://academic.oup.com/pages/standard-publication-reuse-rights
- DOI
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- 10.1246/bcsj.20140168
- 公開者
- Oxford University Press (OUP)
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説明
<jats:title>Abstract</jats:title> <jats:p>Excess volume and speed of sound data for the ternary mixtures were reported at 303.15 K over the entire composition range for three ternary mixtures containing N-methylcyclohexylamine and toluene as common components and 1-alcohols as third component, namely 1-propanol, 1-butanol, and 1-pentanol. The experimental speed of sound and density of ternary mixtures were used to compute isentropic compressibility (ḱs123) and the quantity Δks123, the difference between measured value and that computed from the constituent binary data. Further, the experimental ternary excess volume data were compared with calculated data obtained by empirical relations proposed by Redlich–Kister, Kohler, Tsao–Smith, and Hwang. The results were analyzed on the basis of intermolecular interactions between component molecules and also in terms of constituent binary data.</jats:p>
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 87 (11), 1265-1272, 2014-08-26
Oxford University Press (OUP)
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詳細情報 詳細情報について
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- CRID
- 1360002219096949504
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- NII論文ID
- 130004703932
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- ISSN
- 13480634
- 00092673
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