Spectrochemical Study of Microscopic Crystals. XIII. The Structure of Wolffram’s Red Salt, Pt(NH2·C2H5)4Cl3·2H3O and a Related Compound
-
- Shoichiro Yamada
- Department of Chemistry, Faculty of Science, Osaka University
-
- Ryutaro Tsuchida
- Department of Chemistry, Faculty of Science, Osaka University
書誌事項
- 公開日
- 1956-08-01
- 権利情報
-
- https://academic.oup.com/pages/standard-publication-reuse-rights
- DOI
-
- 10.1246/bcsj.29.894
- 公開者
- Oxford University Press (OUP)
この論文をさがす
説明
<jats:title>Abstract</jats:title> <jats:p>Polarized absorption spectra of Wolffram’s red salt, Pt(EA)4Cl3·2H2O, and a related compound, Pt(EA)4Br3·2H2O, EA being ethylamine, have been determined by Tsuchida-Kobayashi’s microscopic method in the regions covering from 2400 to 7500 Å.</jats:p> <jats:p>Both the compounds, which are supposed to be formulated by [Pt(EA)4][Pt(EA)4X2]X4·4H2O, have been found to show an absorption band that has not been observed with either of the components alone. Moreover, this band is strongly polarized along the needle axis. These relationships may be understood on the assumption that the crystals of these compounds involve infinite chains of ---X—PtIV—X---PtII---X—PtIV—X--- along the needle axis, X being chlorine or bromine.</jats:p> <jats:p>The new absorption at the longer wavelength may be considered as a charge transfer band along the infinite chains as assumed above.</jats:p>
収録刊行物
-
- Bulletin of the Chemical Society of Japan
-
Bulletin of the Chemical Society of Japan 29 (8), 894-898, 1956-08-01
Oxford University Press (OUP)
- Tweet
キーワード
詳細情報 詳細情報について
-
- CRID
- 1360002219097413632
-
- NII論文ID
- 130001959745
-
- ISSN
- 13480634
- 00092673
-
- データソース種別
-
- Crossref
- CiNii Articles
- OpenAIRE
