The Synthesis of 2,7-Bis(dimethylamino)pyrene and -tetrahydropyrene and the Electrical Conductivities of Their Complexes
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- Naomi Ueda
- The Institute of Scientific and Industrial Research, Osaka University
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- Bunji Natsume
- The Institute of Scientific and Industrial Research, Osaka University
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- Kazumi Yanagiuchi
- The Institute of Scientific and Industrial Research, Osaka University
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- Yoshiteru Sakata
- The Institute of Scientific and Industrial Research, Osaka University
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- Toshiaki Enoki
- The Institute for Molecular Science
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- Gunzi Saito
- The Institute for Molecular Science
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- Hiroo Inokuchi
- The Institute for Molecular Science
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- Soichi Misumi
- The Institute of Scientific and Industrial Research, Osaka University
書誌事項
- 公開日
- 1983-03-01
- 権利情報
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- https://academic.oup.com/pages/standard-publication-reuse-rights
- DOI
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- 10.1246/bcsj.56.775
- 公開者
- Oxford University Press (OUP)
この論文をさがす
説明
<jats:title>Abstract</jats:title> <jats:p>New π-donors containing a pyrene or a tetrahydropyrene ring were synthesized by means of a unique transannular reaction of the corresponding [2.2]metacylcophane derivatives. The CT complexes of these donors with a series of TCNQ derivatives different in electron affinity were prepared, and their electrical conductivities on single crystals were measured. The highest conductivity (0.36 Ω−1 cm−1) was that of the tetrahydropyrene derivative-TCNQ complex. It was reconfirmed that the partial charge-transfer from a donor to an acceptor is very important for high conductivity.</jats:p>
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 56 (3), 775-779, 1983-03-01
Oxford University Press (OUP)
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詳細情報 詳細情報について
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- CRID
- 1360002219102113152
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- NII論文ID
- 130001985414
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- ISSN
- 13480634
- 00092673
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- データソース種別
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