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- Shigeru Takagi
- Department of Chemistry, Faculty of Science, The University of Tokyo
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- T Ken Miyamoto
- Department of Chemistry, Faculty of Science, The University of Tokyo
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- Yukiyoshi Sasaki
- Department of Chemistry, Faculty of Science, The University of Tokyo
書誌事項
- 公開日
- 1985-02-01
- 権利情報
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- https://academic.oup.com/pages/standard-publication-reuse-rights
- DOI
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- 10.1246/bcsj.58.447
- 公開者
- Oxford University Press (OUP)
この論文をさがす
説明
<jats:title>Abstract</jats:title> <jats:p>A new model compound “tulip garden” porphyrin, has a long half-lifetime, thus satisfying the demand for the synthetic analogue of myoglobin. At the same time, “tulip garden” porphyrin has high O2 affinities as compared to other protected porphyrins; especially, its Co(II) complex shows almost the same affinity (P1/2O2) as coboglobins. The difference in oxygen affinities between “tulip garden” and “picket fence-type” porphyrins can be ascribed to the bulkiness of pendant groups. The strong “side” influence of the adamantyl group can be expected to bring about a high O2 affinity.</jats:p>
収録刊行物
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- Bulletin of the Chemical Society of Japan
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Bulletin of the Chemical Society of Japan 58 (2), 447-454, 1985-02-01
Oxford University Press (OUP)
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詳細情報 詳細情報について
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- CRID
- 1360002219102484992
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- NII論文ID
- 130001983905
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- ISSN
- 13480634
- 00092673
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- データソース種別
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- Crossref
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