Side-Chain Bromination of Diphenylmethanes, 1,2-Diphenylethanes, and 10,11-Dihydro-5<i>H</i>-dibenzo[<i>a</i>,<i>d</i>]cycloheptenes with <i>N</i>-Bromosuccinimide under Irradiation of a Tungsten Lamp

DOI DOI PDF 参考文献6件
  • Shuntaro Mataka
    Institute of Advanced Material Study, Kyushu University6-1 Kasuga-kohen, Kasuga 816
  • Guo-Bin Liu
    Department of Molecular Science and Technology, Graduate School of Engineering Sciences, Kyushu University6-1 Kasuga-kohen, Kasuga 816
  • Akiyoshi Tori-i
    Kurume National College of Technology1342, Komorino, Kurume 830
  • Masashi Tashiro
    Institute of Advanced Material Study, Kyushu University6-1 Kasuga-kohen, Kasuga 816

書誌事項

公開日
1994-08-01
権利情報
  • https://academic.oup.com/pages/standard-publication-reuse-rights
DOI
  • 10.1246/bcsj.67.2336
  • 10.1002/chin.199504092
公開者
Oxford University Press (OUP)

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<jats:title>Abstract</jats:title> <jats:p>The photothermal bromination of diphenylmethane and methyl derivatives with N-bromosuccinimide afforded benzophenone and (polybromomethyl)benzophenones via the hydrolysis of dibromodiphenylmethanes. 1,2-Diphenylethane and p-t-butyl derivative gave dibromostilbenes, while the o-methyl derivative afforded bis(dibromomethyl)dibromodiphenylethane. 10,11-Dihydro-5H-dibenzo[a,d]cycloheptene gave 9-bromodibenzocycloheptenone, which was also obtained in the bromination of 10,11-dihydro-5H-dibenzo[a,d]cyclohepten-5-one.</jats:p>

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