Correlation between Chemical and Physical Pressures on Charge Bistability in [Pd(en)<sub>2</sub>Br](Suc-C<sub><i>n</i></sub>)<sub>2</sub>·H<sub>2</sub>O
-
- Shohei Kumagai
- Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aza-Aoba, Aramaki, Aoba-ku, Sendai 980-8578, Japan
-
- Shinya Takaishi
- Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aza-Aoba, Aramaki, Aoba-ku, Sendai 980-8578, Japan
-
- Hiroaki Iguchi
- Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aza-Aoba, Aramaki, Aoba-ku, Sendai 980-8578, Japan
-
- Brian K. Breedlove
- Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aza-Aoba, Aramaki, Aoba-ku, Sendai 980-8578, Japan
-
- Takuya Kaneko
- Department of Applied Physics, Graduate School of Engineering, Nagoya University, Chikusa Ward, Furocho, Nagoya 464-0814, Japan
-
- Hiroshi Ito
- Department of Applied Physics, Graduate School of Engineering, Nagoya University, Chikusa Ward, Furocho, Nagoya 464-0814, Japan
-
- Shin-ichi Kuroda
- Department of Applied Physics, Graduate School of Engineering, Nagoya University, Chikusa Ward, Furocho, Nagoya 464-0814, Japan
-
- Masahiro Yamashita
- Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aza-Aoba, Aramaki, Aoba-ku, Sendai 980-8578, Japan
書誌事項
- 公開日
- 2017-12-11
- 資源種別
- journal article
- DOI
-
- 10.1021/acs.inorgchem.7b02566
- 公開者
- American Chemical Society (ACS)
この論文をさがす
説明
Hydrostatic (physical) pressure effects on the electrical resistivity of a bromido-bridged palladium compound, [Pd(en)2Br](Suc-C5)2·H2O, were studied. The charge-density-wave to Mott–Hubbard phase transition temperature (TPT) steadily increased with pressure. By a comparison of the effects of the chemical and physical pressures on TPT, it was estimated that the chemical pressure by unit alkyl chain length, i.e., the number of carbon atoms in the alkyl chains within the counterion, corresponded to ca. 1.3 kbar of the physical pressure.
収録刊行物
-
- Inorganic Chemistry
-
Inorganic Chemistry 57 (1), 12-15, 2017-12-11
American Chemical Society (ACS)
関連未分類成果物
- Tweet
詳細情報 詳細情報について
-
- CRID
- 1360004233126370560
-
- ISSN
- 1520510X
- 00201669
-
- 資料種別
- journal article
-
- データソース種別
-
- Crossref
- KAKEN
- OpenAIRE
- IRDB