Three-Dimensional Architectures of [Mn<sup>II</sup>Cr<sup>III</sup>(oxalate)<sub>3</sub>]<sup>−</sup> Complexes with Cage-Type Networks Surrounding Supramolecular Cations
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- Toru Endo
- Graduate School of Environmental Science, Hokkaido University, N10W5, Kita-ku, Sapporo, 060-0810, Japan
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- Kazuya Kubo
- Graduate School of Environmental Science, Hokkaido University, N10W5, Kita-ku, Sapporo, 060-0810, Japan
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- Masashi Yoshitake
- Research Institute for Electronic Science, Hokkaido University, N20W10, Kita-ku, Sapporo, 001-0020, Japan
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- Shin-ichiro Noro
- Graduate School of Environmental Science, Hokkaido University, N10W5, Kita-ku, Sapporo, 060-0810, Japan
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- Norihisa Hoshino
- Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai, 980-8577, Japan
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- Tomoyuki Akutagawa
- Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai, 980-8577, Japan
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- Takayoshi Nakamura
- Graduate School of Environmental Science, Hokkaido University, N10W5, Kita-ku, Sapporo, 060-0810, Japan
書誌事項
- 公開日
- 2015-02-05
- 資源種別
- journal article
- DOI
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- 10.1021/cg501560z
- 公開者
- American Chemical Society (ACS)
この論文をさがす
説明
Metal–organic network structure based on oxalate bridges {[MnIICrIII(oxalate)3]−}∞ and supramolecular cations (H2PPD2+)(benzo[18]crown-6)2[MnCr(oxalate)3](CH3OH)(CH3CN)2 (1) and (o-FAni+)2(DCH[18]crown-6)2[Mn(CH3OH)Cr(oxalate)3][MnCr(oxalate)3](CH3OH) (2), where H2PPD2+, o-FAni+, and DCH[18]crown-6 denote p-phenylenediammonium2+, o-fluoroanilinium+, and cis-syn-cis-dicyclohexano[18]crown-6, respectively, were synthesized. The crystal structure of 1 was the combination of [Mn(Λ)Cr(Λ)(oxalate)3]− and [Mn(Λ)Cr(Δ)(oxalate)3]−, whereas that of crystal 2 was the combination of [Mn(Λ)(CH3OH)Cr(Δ)(oxalate)3] and [Mn(Λ)Cr(Δ)(oxalate)3]. Large flexible supramolecular cations provide the three-dimensional structure of {[MnIICrIII(oxalate)3]−}∞, which is different from the two-dimensional honeycomb structure often observed for {[MnIICrIII(oxalate)3]−}∞ complexes. Temperature-dependent magnetic susceptibilities of the complexes 1 and 2 exhibited ferromagnetic behaviors following the Curie–Weiss law (C = 11.5 cm3 K mol...
収録刊行物
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- Crystal Growth & Design
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Crystal Growth & Design 15 (3), 1186-1193, 2015-02-05
American Chemical Society (ACS)
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詳細情報 詳細情報について
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- CRID
- 1360004233178035584
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- ISSN
- 15287505
- 15287483
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- 資料種別
- journal article
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- データソース種別
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- Crossref
- KAKEN
- OpenAIRE
