In Situ Generation of Functionality in a Reactive Haloalkane-Based Ligand for the Design of New Porous Coordination Polymers
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- Prakash Kanoo
- Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Nishikyo-ku, Katsura, Kyoto 615-8510, Japan
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- Ryotaro Matsuda
- Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Nishikyo-ku, Katsura, Kyoto 615-8510, Japan
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- Hiroshi Sato
- Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Nishikyo-ku, Katsura, Kyoto 615-8510, Japan
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- Liangchun Li
- Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Nishikyo-ku, Katsura, Kyoto 615-8510, Japan
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- Hyung Joon Jeon
- Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Nishikyo-ku, Katsura, Kyoto 615-8510, Japan
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- Susumu Kitagawa
- Institute for Integrated Cell-Material Sciences (WPI-iCeMS), Kyoto University, Nishikyo-ku, Katsura, Kyoto 615-8510, Japan
書誌事項
- 公開日
- 2013-09-09
- 資源種別
- journal article
- DOI
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- 10.1021/ic401924d
- 公開者
- American Chemical Society (ACS)
この論文をさがす
説明
Herein, we report new porous coordination polymers (PCPs) via a facile synthetic approach called "in situ generation of functionality in the ligand". Upon a synthetic process of PCPs, a neutral (-CH2OH) or a cationic functionality (-CH2-[4,4'-bipyridine](+)) was generated on a isophthalate ligand from a reactive haloalkane (-CH2Br) moiety, affording two new PCPs. The PCPs have two-dimensional layered structures with large potential solvent-accessible voids for CO2 adsorption.
収録刊行物
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- Inorganic Chemistry
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Inorganic Chemistry 52 (19), 10735-10737, 2013-09-09
American Chemical Society (ACS)
