A long-tethered (P–B–P)-pincer ligand: synthesis, complexation, and application to catalytic dehydrogenation of alkanes
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- Enrique Huang Kwan
- Department of Applied Chemistry
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- Yasushi Jack Kawai
- Department of Applied Chemistry
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- Sei Kamakura
- Department of Applied Chemistry
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- Makoto Yamashita
- Department of Applied Chemistry
書誌事項
- 公開日
- 2016
- 資源種別
- journal article
- DOI
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- 10.1039/c6dt02075e
- 公開者
- Royal Society of Chemistry (RSC)
この論文をさがす
説明
<p>A new long-tethered boron-containing (P–B–P)-pincer ligand has been synthesized. This ligand was introduced to Ir to form (P–B–P)Ir(H)Cl complex. Subsequent reaction with <italic>n</italic>BuLi led to the formation of dihydride complex (P–B–P)Ir(H)2. Both complexes were found to be moderately active for the catalytic dehydrogenation of alkanes.</p>
収録刊行物
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- Dalton Transactions
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Dalton Transactions 45 (40), 15931-15941, 2016
Royal Society of Chemistry (RSC)
