Stereo correlated dynamics in the energy transfer process of aligned N2 (A 3Σu+) + oriented NO (X 2Π, Ω = 1/2) → NO (A 2Σ+) + N2 (X 1Σg+)
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- H. Ohoyama
- Osaka University Department of Chemistry, Graduate School of Science, , Toyonaka, Osaka 560-0043, Japan
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- S. Maruyama
- Osaka University Department of Chemistry, Graduate School of Science, , Toyonaka, Osaka 560-0043, Japan
書誌事項
- 公開日
- 2012-08-09
- 資源種別
- journal article
- DOI
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- 10.1063/1.4739273
- 公開者
- AIP Publishing
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説明
<jats:p>Steric effect for the NO (A 2Σ+) formation in the aligned N2 (A 3Σu+) + oriented NO (X 2Π, Ω = 1/2) reaction has been observed as a function of the mutual orientational configurations between the two molecular reactants in the collision frame. Multidimensional molecular steric opacity function has been determined. A significant NO (X 2Π) alignment dependence is recognized in contrast with little dependence on NO (X 2Π) orientation. The NO alignment selectivity turns out to depend on the N2 (A 3Σu+) alignment: The axial configuration of NO (X 2Π) is favorable for the axial and sideways configurations of N2 (A 3Σu+), while the sideways configuration of NO (X 2Π) is favorable for the oblique configuration of N2 (A 3Σu+) at an orientation angle of ${\rm \theta }_{{\rm v}_{\rm R} }$θvR ∼ 45°. with respect to the relative velocity (vR).</jats:p>
収録刊行物
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- The Journal of Chemical Physics
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The Journal of Chemical Physics 137 (6), 064311-, 2012-08-09
AIP Publishing
