Birch Reduction of Arenes Using Sodium Dispersion and DMI under Mild Conditions

DOI PDF 被引用文献3件 参考文献66件
  • Sobi Asako
    Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University, 3-1-1 Tsushimanaka, Kita-ku, Okayama 700-8530 , Japan
  • Ikko Takahashi
    RIKEN Center for Sustainable Resource Science, 2-1 Hirosawa, Wako, Saitama 351-0198 , Japan
  • Takashi Kurogi
    Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University, 3-1-1 Tsushimanaka, Kita-ku, Okayama 700-8530 , Japan
  • Yoshiaki Murakami
    KOBELCO ECO-Solutions Co., Ltd., 4-78-1 Wakinohama-cho, Chuo-ku, Kobe 651-0072 , Japan
  • Laurean Ilies
    RIKEN Center for Sustainable Resource Science, 2-1 Hirosawa, Wako, Saitama 351-0198 , Japan
  • Kazuhiko Takai
    Division of Applied Chemistry, Graduate School of Natural Science and Technology, Okayama University, 3-1-1 Tsushimanaka, Kita-ku, Okayama 700-8530 , Japan

説明

<jats:title>Abstract</jats:title> <jats:p>An easy-to-handle sodium dispersion in paraffin oil (SD), in combination with inexpensive and environmentally benign 1,3-dimethyl-2-imidazolidinone (DMI) as an additive enables the Birch-type reduction of a variety of arenes with high yields, selectivity, and tolerance of functionality such as ether, alcohol, amine, amide, and carboxylic acid.</jats:p>

収録刊行物

  • Chemistry Letters

    Chemistry Letters 51 (1), 38-40, 2021-10-07

    Oxford University Press (OUP)

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